Description:
Cancrinite is one of the rarer members of the feldspathoid
group of minerals. Minerals whose chemistries are close
to that of the alkali feldspars but are poor in silica
(SiO2) content, are called feldspathoids. As a result
or more correctly as a function of the fact, they are
found in silica poor rocks containing other silica poor
minerals and no quartz . If quartz were present when
the melt was crystallizing, it would react with any
feldspathoids and form a feldspar. Localities that have
feldspathoids are few.
Cancrinite is unusual in that it is one of the few silicate
minerals to have a carbonate ion (CO3 -2) present in
its structure. It is because of the carbonate ion that
it will effervescence in warm hydrochloric acid. The
acid reacts with the carbonate ion to liberate carbon
dioxide (CO2) gas which forms the bubbles. The effervescence
is diagnostic as almost no other silicates will do this,
although it is common in the carbonates .
Although feldspathoids are known to both extrusive and
intrusive igneous rocks, cancrinite is found almost
exclusively in intrusive or plutonic rocks. This may
be due to the tremendous pressures required to force
the large carbonate ions into the structure of cancrinite.
Cancrinite will also contain some percentages of sulfate
ions (SO4 -2) and chlorine ions (Cl -1); two other large
ions. Feldspathoids are similar to zeolites in that
their wide open structures allow large ions to be incorporated
into them. |